A. Graham Lappin

A. Graham Lappin

Inorganic Reaction Mechanisms

Biography

1991-present
Professor, University of Notre Dame
1986-1991
Associate Professor, University of Notre Dame
1982-1986
Assistant Professor, University of Notre Dame
1978-1982
Lecturer, University of Glasgow, Scotland
1977-1978
Postdoctoral Research Fellow, University of Leeds, England
1975-1977
Postdoctoral Research Associate, Purdue University
1975
Ph.D. in Inorganic Chemistry, University of Glasgow, Scotland
1972
B.Sc. in Chemistry, University of Glasgow, Scotland

Selected Awards

2015
Joyce Award for Excellence in Undergraduate Teaching
2011
Elected Fellow of the Royal Society of Chemistry
2007
Faculty Award, University of Notre Dame
2004
Kaneb Teaching Award

Research Interests

Professor Lappin has worked in the area of mechanistic inorganic chemistry for the past twenty-five years. His interests cover both substitution reactions and redox processes of transition metal ion complexes and range from reactions of metalloproteins in biological systems to the corrosion chemistry associated with chemical reactors. Studies of cooperation between multiple reaction centers in chemical reactions have been a long standing area of research, particularly those involving multiple electron transfer or coupled electron and ion transfer.

Over the last decade the Lappin group has investigated phemomena associated with chiral induction in electron transfer and atom transfer reactions involving metal ion complexes and has provided much of the insight required for the interpretation of this effect. The inductions tend to be small but provide a very sensitive mechanistic probe. They occur quite generally in both outer-sphere and inner-sphere reactions.

Work in this area encompasses developments in molecular and chiral recognition and the characterization of weak interactions between metal complexes. These studies have led to the design of novel chiral ligands and investigations of new magnetic materials based on chiral paramagnetic metal complexes.

Recent Papers

  • Maisuls, I., Cabrerizo, F.M., Lappin, A.G., Ruiz, G.T., Ferraudi, G.J. "Photophysical properties of [(norharmane)Re(CO)3 (L)]+ complexes (L = bpy, phen or dppz). Redox behavior of the excited states and their interaction with Calf Thymus DNA" 2018 Journal of Photochemistry and Photobiology A: Chemistry, 364, pp. 169-176. DOI: 10.1016/j.jphotochem.2018.05.007
  • Ragone, F., Gara, P.D., García Einschlag, F.S., Lappin, A.G., Ferraudi, G.J., Wolcan, E., Ruiz, G.T. "Photophysics, photochemistry and thermally-induced redox reactions of a (Pterin)rhenium(I) complex" 2018 Journal of Photochemistry and Photobiology A: Chemistry, 358, pp. 147-156. DOI: 10.1016/j.jphotochem.2018.02.015​​​​​​​
  • Godoy, F., Maldonado, T., Flores, E., Agurto, N., González, R., Ferraudi, G., Lappin, G. "Novel organometallic chalcones functionalized with a crown ether fragment as optical ion chemosensors" 2018 Applied Organometallic Chemistry, 32 (3), e4115. DOI: 10.1002/aoc.4115​​​​​​​
  • Moncada, A.S., Gutiérrez-Pineda, E., Maisuls, I., Ruiz, G.T., Lappin, A.G., Ferraudi, G.J., Wolcan, E. "Photochemical properties of a Re(I) polymer containing dppz in its structure. An interplay between dark and bright states of dppz" 2018 Journal of Photochemistry and Photobiology A: Chemistry, 353, pp. 86-100. DOI: 10.1016/j.jphotochem.2017.11.007
  • Maldonado, T., Godoy, F., Ferraudi, G., Graham Lappin, A. "On the photochemical properties of the organometallic trans cyrhetrenyl chalcone (E). Deceleration of the photoisomerization and quenching of the luminescence effected by the photogenerated cis isomer (Z)" 2018 Inorganica Chimica Acta, 469, pp. 239-244. DOI: 10.1016/j.ica.2017.09.022​​​​​​​
  • Díaz, D.E., Llanos, L., Arce, P., Lorca, R., Guerrero, J., Costamagna, J., Aravena, D., Ferraudi, G., Oliver, A., Lappin, A.G., Lemus, L. "Steric and Electronic Factors Affecting the Conformation of Bimetallic CuI Complexes: Effect of the Aliphatic Spacer of Tetracoordinating Schiff-Base Ligands" 2018 Chemistry - A European Journal, Article in Press. DOI: 10.1002/chem.201802290

Contact Information

  • Professor
  • Office: 264 Stepan Chemistry Hall
  • Phone: 574-631-7820
  • Send an email

Primary Research Areas

Research Specialties